Dynamic mass accountancy modeling of a molten salt reactor using equilibrium thermodynamics.

• Coupling of equilibrium thermodynamics library Thermochimica with dynamic systems modeling tool TRANSFORM. • Mass accountancy in a model of a molten salt reactor. • Modeling of precipitation and off-gassing during molten salt reactor operation. A mechanistic-based mass accountancy model in the context of liquid-fueled molten salt reactors was implemented in the dynamic systems modeling software library TRANSFORM by way of coupling with the equilibrium thermodynamics code Thermochimica. Liquid-fueled molten salt reactors present new challenges for mass accountancy because of the dissolution of fuel and evolved fission products, which may be soluble in the salt, off-gas, or precipitate. Two cases of mass loss from the molten salt were addressed: off-gassing and precipitation. The software implementation was tested through a series of increasingly complex demonstration problems, culminating in a model of the primary fuel and primary coolant loops of the molten salt demonstration reactor. Analysis shows that negligible mass was lost from the salt under normal operating conditions, but an overheating event caused by partial loss of fuel loop cooling resulted in release of measurable amounts of uranium (among other elements) via off-gassing. The tools developed here are primarily aimed at capability development but are readily available for use in further modeling of molten salt reactor concepts. These tools have not yet been validated, and future experimental work to perform this validation is recommended. [ABSTRACT FROM AUTHOR]