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Comparison of nanostructured composite cathodes synthesized by liquid self-assembly and nanosolid mechanical-mixing for solid oxide fuel cell.
- Source :
-
International Journal of Hydrogen Energy . Apr2022, Vol. 47 Issue 35, p15721-15730. 10p. - Publication Year :
- 2022
-
Abstract
- The composite perovskites are promising low/intermediate-temperature solid oxide fuel cell (LT/IT-SOFC) cathode materials, which can combine the complementary advantages of multi-components. Here, novel liquid self-assembly (SA) is compared with nanosolid mechanical-mixing (MM) for the high-performance nanostructured composite. The same composition of the active BaCo 0.96 Zr 0.04 O 2.6+δ (12hBC, 38 mol%) with the stable BaZr 0.82 Co 0.18 O 3-δ (BZC, 62 mol%) is designed to compare the effects of different syntheses on composite properties. The BZC-12hBC (SA) can achieve molecular-level contact of multiple phases, which exhibits superior electrical conductivity, surface and heterointerface activity to those of BZC-12hBC (MM). When further applied on LT/IT-SOFC, the cell with BZC-12hBC (SA) cathode achieves the remarkable peak power densities of 2.06–0.24 W cm−2 at 700–500 °C, while the cell with BZC-12hBC (MM) cathode only exhibits 0.63–0.11 W cm−2. The electrochemical analysis reveals that BZC-12hBC (SA) cathode possesses better oxygen dissociative adsorption and species transportation than those of the BZC-12hBC (MM) cathode. • A self-assembly (SA) method is compared with mechanical mixing for composite. • The SA achieves nanostructured composite of superior oxygen redox properties to MM. • Power density of cell with cathode (SA) is almost 3 times of that with cathode (MM). • The composite (SA) has superior adsorption and transport activity to composite (MM). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03603199
- Volume :
- 47
- Issue :
- 35
- Database :
- Academic Search Index
- Journal :
- International Journal of Hydrogen Energy
- Publication Type :
- Academic Journal
- Accession number :
- 156552345
- Full Text :
- https://doi.org/10.1016/j.ijhydene.2022.03.053