A constitutive model for metallic glasses based on two-temperature nonequilibrium thermodynamics.

• Constitutive model for metallic glass within the framework of irreversible nonequilibrium thermodynamics is developed by extending classical STZ theory. • Deformations of metallic glass under different ambient temperatures and applied strain rates are well predicted. • Mechanisms of deformation mode evolution and shear band formation are reasonably explained. We develop a new finite deformation constitutive model for metallic glass within the framework of irreversible nonequilibrium thermodynamics. To consider the intrinsically out-of-equilibrium characteristics of metallic glass, its total internal energy is divided into two weakly coupled configurational and kinetic subsystems, and configurational temperature coupling with configurational degrees of freedom is introduced as a thermodynamic state variable to characterize the evolution of the disordered structure. Furthermore, the classical shear transformation zone theory is extended by reasonably considering the reverse shear transformation as a form of the relaxation of the strain field, which is stored in the elastic matrix and produced by the constraint of the matrix on shear transformation. With the help of the finite element implementation for the new model, the effectiveness of the proposed model is validated by comparing the modeling stress–strain responses of the macroscopic deformations under different temperatures and strain rates with the experimental results, and the utility of the model for predicting the shear banding behavior of metallic glasses is examined as well. The results therefore show that the constructed constitutive model can not only effectively predict the deformations of metallic glass under different ambient temperatures and applied strain rates, but also reasonably explain the mechanisms of deformation mode evolution and shear band formation. [ABSTRACT FROM AUTHOR]