Efficient fractionation of woody biomass hemicelluloses using cholinium amino acids-based deep eutectic solvents and their aqueous mixtures.

[Display omitted] • Cholinium amino acids-based DESs were designed to fractionate hemicellulose. • Integration of water into DESs enhanced hemicellulose removal. • Effect of water in DESs on structural features of hemicellulose were revealed. • DES aqueous mixtures showed reusability in hemicellulose extraction. Novel and green cholinium amino acids-based deep eutectic solvents (DESs) and their aqueous mixtures were synthesized and employed in deconstructing poplar for hemicellulose fractionation. The effects of water content in DESs on hemicellulose dissociation and structural features were comprehensively investigated, along with the reusability of DESs for treatment. The integration of water into DESs could facilitate hemicellulose fractionation, and the cholinium lysine: urea with 5 wt% water (CL: U-5) demonstrated the best performance with a hemicellulose yield of 59.2%. Further structure analysis revealed that hemicelluloses with various branching degrees and molecular weights were obtained with varying water content of DESs. Furthermore, the CL: U-5 had recyclability and reusability with a 40.5% hemicellulose yield obtained after reused three times. The novel and eco-friendly cholinium amino acids-based DESs treatment provides an effective and sustainable strategy for hemicellulose fractionation from woody biomass. [ABSTRACT FROM AUTHOR]