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Self-supporting copper electrode prepared by ultrasonic impact for hydrogen evolution reaction.
- Source :
-
Journal of Alloys & Compounds . Sep2022, Vol. 916, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- Water electrolysis for hydrogen production requires highly active and inexpensive catalysts. Herein, we combine ultrasonic impact nanocrystallization (UIN) technology with nital etching method to rapidly prepare highly efficient self-supporting Cu electrode with abundant low-angle grain boundaries. When used as a catalyst for hydrogen evolution reaction (HER), the as-prepared electrode exhibits an overpotential of 353 mV at a current density of 10 mA cm−2, which is about 200 mV lower than that of the blank Cu plate. Moreover, the overpotential decreased to 246 mV after the stability test of 100 h, indicating a self-optimizing property. This work paves a new way for the preparation of self-supporting electrode with high performance. • Ultrasonic impact nanocrystalline could be used in catalysis. • Cu self-supporting electrode with high density surface dislocation is prepared. • The dislocation density could be precisely adjusted by controlling the etching time. • Electrode exhibits high HER activity and stability, shows self-optimized performance. • Dislocations have lower hydrogen adsorption free energies than perfect crystals. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 916
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 157119895
- Full Text :
- https://doi.org/10.1016/j.jallcom.2022.165283