On the long decay time of the 7F5 level of Tb3+.

The Tb3+7F 5 level has been shown to play an important role in the energy transfer involving this ion. This is due to the unusually long lifetime of this level which is commonly disregarded when treating energy transfer involving this ion. In this work, we give a rationalized explanation for this phenomenon. It is discussed that the 7F 5 level can be fed by an energy transfer process and the population is trapped due to a low decay rate, which is related to the energy gap to the 7F 6 ground level in the far infrared and the correspondingly low photon density of states. This is in agreement with experimental data from direct measurements of the total decay lifetimes of the 7F 5 level and the emission quantum yields when this level is considered as an energy acceptor in Tb3+ compounds. [Display omitted] • The Tb3+7F 5 level population is rationalized, this is of high relevance in energy transfer processes involving this ion. • The 7F 5 level could have a high population fraction when compared with the 7F 6 ground level. • Multiphonon and radiative rates between 7F J levels were estimated. • A rate equation model was used to estimate the 7F 5 population fraction. [ABSTRACT FROM AUTHOR]