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Anion-induced two stable isostructural Cd(II) LMOFs based on benzotriazole with the highly selective detection of Fe3+ ions.
- Source :
-
New Journal of Chemistry . 6/14/2022, Vol. 46 Issue 22, p10927-10933. 7p. - Publication Year :
- 2022
-
Abstract
- Two new LMOFs, [Cd9(BTA)6(5-tbuip)6O2]n (LMOF-1) and [Cd3(BTA)2(5-tbuip)2]n (LMOF-2) (BTA = 1H-benzotriazole, 5-tbuip = 5-tert-butylisophthalic acid), have been synthesized by a solvothermal method. The different anions of cadmium salts lead to two isostructural LMOFs. Fe3+ could be detected by LMOF-1 with N-rich sites, which possessed a high quenching coefficient (Ksv) of up to 1.87 × 105 M−1. The Ksv value for the detection of Fe3+ is better than or comparable to those reported in the literature. Since LMOF-2 had a larger pore size compared to that of LMOF-1, it could detect Cr2O72− with a higher Ksv than LMOF-1. In addition, LMOF-1 is closer to white light, which means that it has potential application in white light-emitting diodes (WLEDs). [ABSTRACT FROM AUTHOR]
- Subjects :
- *BENZOTRIAZOLE
*LIGHT emitting diodes
*IONS
*CADMIUM
*ANIONS
Subjects
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 46
- Issue :
- 22
- Database :
- Academic Search Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 157296821
- Full Text :
- https://doi.org/10.1039/d2nj01514e