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Blue-emitting 0D Cs3ZnX5 (X = Cl, Br) perovskite nanocrystals based on self-trapped excitons.
- Source :
-
Journal of Luminescence . Sep2022, Vol. 249, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- All-inorganic Pb-free halide perovskites have recently received extensive attention due to their unique structures and optoelectronic properties. However, the realization of pure-blue emitting perovskite nanocrystals (NCs) with satisfactory stability and rational interpretation for their corresponding self-trapped excitons (STEs) emissions remains an arduous task. Herein, a modified hot-injection method is proposed to prepare a new family of zero-dimensional (0D) Cs 3 ZnX 5 (X = Cl, Br) perovskite NCs with pure-blue and sky-blue photoluminescence (PL) emissions. Benefitting from the 0D tetragonal-phase structure, the Cs 3 ZnX 5 NCs possess outstanding long-term stability in ambient air conditions. We employ the experimental results and first-principles calculations to confirm that the blue STEs emission of Cs 3 ZnX 5 NCs is dominated by the halide vacancies (V X) in [ZnX 4 ]2- tetrahedra. Our findings not only provide a simple and valid method to control the synthesis of blue-emitting 0D Zn-based perovskite NCs, but also clarify their underlying PL mechanism. • A new family of zero-dimensional Cs 3 ZnX 5 (X = Cl, Br) perovskite nanocrystals. • Perovskites with stable pure-blue and sky-blue photoluminescence emissions. • Self-trapped excitons luminescence induced by halide vacancies of perovskites. • A universal luminescence mechanism for zero-dimensional Zn-based halide perovskites. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00222313
- Volume :
- 249
- Database :
- Academic Search Index
- Journal :
- Journal of Luminescence
- Publication Type :
- Academic Journal
- Accession number :
- 157438912
- Full Text :
- https://doi.org/10.1016/j.jlumin.2022.119048