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Preparation and properties of Sr(CrMnFeCoNi)3O4 and Sr(MgAlTiCrFe)12O19 high entropy strontium ferrite systems and valance state analysis.
- Source :
-
Ceramics International . Aug2022, Vol. 48 Issue 16, p23963-23974. 12p. - Publication Year :
- 2022
-
Abstract
- Two high-entropy ferrite ceramic systems, Sr(CrMnFeCoNi) 12 O 19 and Sr(MgAlTiCrFe) 12 O 19 , were designed according to AB 12 O 19 composition and synthesised using elevated-temperature solid phase reaction. The B-site was loaded with five atoms in equal proportions. We focused on preparing high-entropy hexagonal magnetoplumbite strontium ferrites. However, spinel structure significantly formed in the Sr(CrMnFeCoNi) 12 O 19 system. The extruded strontium outside the lattice pulled out a part of chromium, causing phase separation and element segregation. The strontium extrusion outside the lattice and non-formation of hexagonal ferrite, which was reported for the first time, could be attributed to the electrovalence change in the elements. First-principles calculation of the (CrMnFeCoNi) 3 O 4 spinel system was used to analyse the band structure and density state. After entropy engineering design, it was mutated into a wide direct band gap (2.3 eV at 0 K). Although the non-magnetic elements reduced the magnetic performance, they significantly improved the mechanical performance with a flexural strength of 208.7 ± 0.9 MPa. These results may contribute to the element selection and preparation of high-entropy strontium ferrites. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 48
- Issue :
- 16
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 157591882
- Full Text :
- https://doi.org/10.1016/j.ceramint.2022.05.071