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Structure-Performance Evolution of Cobalt-Ammonia Activated Carbon Catalyst for Ethylene Oligomerization.
- Source :
-
Catalysis Letters . Jul2022, Vol. 152 Issue 7, p2131-2140. 10p. - Publication Year :
- 2022
-
Abstract
- The structure-performance evolution of Co/N-AC catalyst during ethylene oligomerization was investigated in detail. It was found that the catalytic activity sharply decreased in the first 30 h with the ethylene conversion decreasing from 64 to 4%. Butene selectivity increased gradually in the first 10 h then remained about 74%, while the selectivity for hexene and octene exhibited an opposite trend. The ratio of α-olefin to isomers for butene increased greatly with time on stream and most of the generated butene was 1-butene. Based on the structure characterization at different reaction stages, CoOx was suggested to be major active phase and the coverage of long-chain hydrocarbons as well as the loss of surface CoOx active sites due to size growth of Co3O4 nanoparticles were the main reasons for catalytic deactivation. The structure-performance evolution of Co/N-AC catalyst during ethylene oligomerization was investigated and the coverage of long-chain hydrocarbons as well as the loss of surface CoOx active sites due to size growth of Co3O4 nanoparticles were the main reasons for catalytic deactivation [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 1011372X
- Volume :
- 152
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Catalysis Letters
- Publication Type :
- Academic Journal
- Accession number :
- 157775856
- Full Text :
- https://doi.org/10.1007/s10562-021-03790-7