Vital Role of Synthesis Temperature in Co–Cu Layered Hydroxides and Their Fenton-like Activity for RhB Degradation.

Cu and Co have shown superior catalytic performance to other transitional elements, and layered double hydroxides (LDHs) have presented advantages over other heterogeneous Fenton catalysts. However, there have been few studies about Co–Cu LDHs as catalysts for organic degradation via the Fenton reaction. Here, we prepared a series of Co–Cu LDH catalysts by a co-precipitation method under different synthesis temperatures and set Rhodamine B (RhB) as the target compound. The structure-performance relationship and the influence of reaction parameters were explored. A study of the Fenton-like reaction was conducted over Co–Cu layered hydroxide catalysts, and the variation of synthesis temperature greatly influenced their Fenton-like catalytic performance. The Co–Cut=65°C catalyst with the strongest LDH structure showed the highest RhB removal efficiency (99.3% within 30 min). The change of synthesis temperature induced bulk-phase transformation, structural distortion, and metal–oxygen (M–O) modification. An appropriate temperature improved LDH formation with defect sites and lengthened M–O bonds. Co–Cu LDH catalysts with a higher concentration of defect sites promoted surface hydroxide formation for H2O2 adsorption. These oxygen vacancies (Ovs) promoted electron transfer and H2O2 dissociation. Thus, the Co–Cu LDH catalyst is an attractive alternative organic pollutants treatment. [ABSTRACT FROM AUTHOR]