Hydrothermal carbonization improves the quality of biochar derived from livestock manure by removing inorganic matter.

The application of hydrothermal carbonization to improve biomass-derived energy sources is crucial because of insufficient supplies of fossil fuels and concerns associated with the impact of fossil fuels on the environment. Hydrothermal carbonization technology has been developed to circumvent the energy-intensive drying step required for the thermal conversion of high-moisture organic feedstocks into fuel. In this study, the quality of livestock manure was upgraded, and its energy density was increased through hydrothermal carbonization at various temperatures. The evolution of waste biomass under hydrothermal carbonization was chemically analyzed. The increased carbon content of the resulting biochar upgraded its fuel properties, leading to energy savings in the treatment process. After hydrothermal carbonization, the H/C and O/C ratios were lower owing to chemical conversion. The optimal temperature for hydrothermal carbonization was approximately 220 °C. The inorganic content resulted in a lowered degree of agglomeration and reduced the likelihood of fouling during combustion. The thermogravimatric analysis also provided the changing combustion characteristics due to the increased fixed carbon content. Fourier transform infrared spectra revealed that hydrothermal carbonization reaction reduced the numbers of C–O and C–H functional groups and increased the number of aromatic C–H functional groups. The equilibrium moisture content decreased rapidly when hydrothermal carbonization was conducted at temperatures higher than 200 °C, and the initial moisture content was reduced by 75% after hydrothermal carbonization at 300 °C. • Livestock manure production and associated environmental regulations haves increased. • Hydrothermal carbonization was used to upgrade the livestock manure for the fuel. • The combustion performance of biochars was enhanced. • The agglomeration of biochars decreased due to reduction of inorganic matters. • The equilibrium moisture content of biochars decreased due to reduction in hydrophilic groups. [ABSTRACT FROM AUTHOR]