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Free-standing 3D core-shell architecture of Ni3S2@NiCoP as an efficient cathode material for hybrid supercapacitors.
- Source :
-
Journal of Colloid & Interface Science . Nov2022, Vol. 625, p565-575. 11p. - Publication Year :
- 2022
-
Abstract
- [Display omitted] The design and discovery of free-standing hybrid electrode materials with large absolute capacity and high cycling stability for energy storage become desirable and are still challenging. In this work, we demonstrate that the hybrid supercapacitor (HSC) device is assembled by 3D core–shell hierarchical nanorod arrays of Ni 3 S 2 @NiCoP nanocomposite for the first time. The Ni 3 S 2 @NiCoP nanocomposite is successfully synthesized through a facile stratagem containing hydrothermal process and the subsequent electrodeposition method. The 3D architecture of Ni 3 S 2 @NiCoP hybrid electrode composed of vertically aligned "hyperchannel" 1D Ni 3 S 2 nanorods and highly conductive interconnected 2D nanosheets of NiCoP is beneficial to fast electron transfer kinetics, thus leading to enhancing the ionic and electronic conductivity, kinetics of redox reaction, and synergistic behavior of active species. The fabricated HSC device with Ni 3 S 2 @NiCoP electrode delivers outstanding areal capacity of 109 µAh cm−2 at a current density of 1 mA cm−2, brilliant energy density of 74.9 Wh kg−1 at a power density of 700 W kg−1, and prominent cyclic performance of 92% capacity retention even after 144-h floating test. This work demonstrates that the core–shell hierarchical nanorod arrays of Ni 3 S 2 @NiCoP can be viewed as one of the novel battery-type electrode materials for high-performance HSCs. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00219797
- Volume :
- 625
- Database :
- Academic Search Index
- Journal :
- Journal of Colloid & Interface Science
- Publication Type :
- Academic Journal
- Accession number :
- 157992241
- Full Text :
- https://doi.org/10.1016/j.jcis.2022.06.020