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Boosted photoelectric cathodic protection exerted by 3D TiO2/AgInS2/In2S3 nanomultijunction for pure copper in NaCl solution.
- Source :
-
Journal of Applied Electrochemistry . Sep2022, Vol. 52 Issue 9, p1353-1368. 16p. - Publication Year :
- 2022
-
Abstract
- The global annual consumption of marine metal corrosion is a significant challenge to the service life of metals and the development of marine strategies. A tri-dimensional AgInS2/In2S3 co-modified TiO2 nanobush (NB) superstructure photoanode is constructed. It shows superior photoelectric cathodic protection (PECP) characteristic for pure copper whose self-corrosion potential is more negative in simulated natural marine environment without additional any hole scavengers under simulated solar light illumination. Origin from the more negative energy level potential of AgInS2/In2S3, the quasi-Fermi level of the photogenerated electrons of TiO2 NB/AgInS2/In2S3 was pull to a more negative position, reinforcing the transmission of photogenerated electrons to the pure copper whose self-corrosion potential is more negative. The sensitizer AgInS2 together with the assistant layer In2S3 dramatically enhances the PECP performance of TiO2 NB/AgInS2/In2S3. The tri-dimensional ultrafine branch-like architecture of TiO2 NB with the nanoparticles quickens the collection and transfer of photogenerated electrons to the metallic pure copper. This environmentally friendly 3D photoanode structure provides a good reference for the optimized construction of photoelectric materials for marine metal corrosion protection. The tri-dimensional AgInS2/In2S3 co-modified TiO2 nanobush superstructure photoanode possesses superior photoelectric cathodic protection characteristic for pure cooper whose self-corrosion potential is more negative in simulated marine environment under simulated solar light illumination. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0021891X
- Volume :
- 52
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Journal of Applied Electrochemistry
- Publication Type :
- Academic Journal
- Accession number :
- 158062102
- Full Text :
- https://doi.org/10.1007/s10800-022-01717-7