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Quasi-ohmic contact formation assisted by the back contact with Cu2Te nanoparticles@reduced graphene oxide composites for highly efficient CdTe solar cells.
- Source :
-
Journal of Alloys & Compounds . Nov2022, Vol. 921, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- Composite materials based on reduced graphene oxide decorated with cuprous telluride nanoparticles (Cu 2 Te NPs@rGO) were fabricated using a facilitated two-step method. A back-contact layer was formed using a spin-coating method for cadmium telluride (CdTe) solar cells. This research is aimed to improve the photovoltaic performance of a device containing Cu 2 Te NPs@rGO/Au back contacts. Cu 2 Te NPs, as the active copper diffusion source, dope and passivate the interfaces and grain boundaries of CdTe to form the p+-layer, which can reduce the recombination centers and back-contact barrier height. Simultaneously, the reduced graphene oxide (rGO), as a buffer and carrier transport layer, prevents excessive copper diffusion during the annealing process and improves the hole collection capacity. The p-type layer formed by the rGO contact with the Au film enhances hole transport and facilitates a low-resistance contact formation, forming a quasi-ohmic contact, and increases the open-circuit voltage and short-circuit current density. Cu 2 Te NPs@rGO/Au back contacts significantly improved the photovoltaic performance (E ff : 16.5%, V oc : 830 mV, J sc : 27.13 mA/cm2, fill factor: 73.3%, area: 0.24 cm2). The composites retain properties of Cu 2 Te NPs and rGO. Their multifunctional properties reveal the potential of Cu 2 Te NPs@rGO as the back contact and broaden the application of graphene-based composites in photovoltaic devices. Additionaly, the preparation of graphene-based composites and their application as back contact is simple and convenient. • The Cu 2 Te NPs@rGO composites is synthesized by a facilitated two-step method. • The Cu 2 Te NPs@rGO composites is firstly used as the back contact for CdTe solar cells. • Cu 2 Te NPs can effectively dope the CdTe layer, and rGO/Au can reduce the barrier height. • A quasi-ohmic contact is formed by the Cu 2 Te NPs@rGO composites. • A significant enhanced performance (e.g., Eff: 16.5%, V oc : 830 mV, J sc : 27.13 mA/cm2, FF: 73.3%, area: 0.24 cm2) is achieved for CdTe solar cells. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 921
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 158307598
- Full Text :
- https://doi.org/10.1016/j.jallcom.2022.166100