Geochemistry and accumulation of Jurassic oil in the central Junggar Basin, western China.

The central Junggar Basin in western China is unique because it provides insights into the geochemistry of oil from Jurassic coal measures. The analysis of TOC, Rock-Eval pyrolysis, gas chromatography-mass spectrometry (GC-MS), and carbon isotopes was performed to characterize the oil geochemistry and evaluate the hydrocarbon generation potential of source rocks in a coal-bearing formation. Fluid inclusions, fluorescence microscopy, and burial-thermal history were also used to study the oil generation and charging histories. The results show that the mudstone of the Badaowan Formation is the main source rock of the Jurassic and has relatively high hydrocarbon generation potential. The Jurassic oil in the Zhong-4 Block is moderately mature, with an equivalent Ro of about 0.75%. The oil is characterized by heavy carbon isotopes, a predominance of Pr over the Ph, low abundances of trisnorhopane (Ts), tricyclic terpanes and gammacerane, predominance of C 29 steranes among regular steranes, a preponderance of naphthalene and its alkylated analogues in aromatic compounds, and abundant polycyclic compounds. Such geochemical data indicate a contribution of Jurassic humic type organic matter to the oil. The mudstone in the Badaowan Formation started generating hydrocarbons in the Early Cretaceous and reached the peak of hydrocarbon generation in the middle Cretaceous. One major hydrocarbon charging episode is suggested in the Late Cretaceous and another in the early Neogene. The Fukang Depression in the south is the source kitchen, and oil migrates in a direction of southwest to northeast through faults and sandstone carrier beds. • The Jurassic mudstones and oils are mostly within the oil window. • The mudstone in Badaowan Formation is the primary Jurassic source rock. • Unique biomarker characteristics of the Jurassic oil are demonstrated. • The Jurassic oil shows heavy carbon isotopes (δ 13 C > -28‰). • Two major hydrocarbon charging periods for the Jurassic reservoirs are suggested. [ABSTRACT FROM AUTHOR]