Sequence stratigraphy and paleoenvironmental significance of the Neoproterozoic Bambui Group, Central Brazil.

• Re-interpretation of the paleoenvironmental evolution of the São Francisco Basin. • Results indicate a depositional age for the Bambui Group of > 550 Ma, significantly older than recently reported. • Six sequences record the Marinoan and Gaskiers glaciations and track oxygen fluctuations through the Ediacaran. • Loess form most of the siltstones and stimulated photosynthetic oxygen production in surface waters. The Bambui Group is a ca. 2,000 m-thick mixed biochemical-siliciclastic sedimentary succession that accumulated in the Sao Francisco Basin, central Brazil. Its age is contentious, but deposition during the Cryogenian-Ediacaran (ca. 635–550 Ma) is consistent with a new sequence stratigraphic model presented herein and previously published geochemical and structural data. Six stratigraphic sequences are recognized that record depositional evolution from an epeiric sea to foreland basin during the Marinoan snowball glaciation (ca. 635 Ma) to shortly after the Gaskiers (ca. 580 Ma) glaciation. Although this stratigraphic architecture differs from the classic lithostratigraphic and more recent chemostratigraphic and sequence stratigraphic interpretations of the Bambui Group, it is supported by correlation to other Cryogenian-Ediacaran successions globally. Collectively, these six sequences preserve a robust record of seawater redox structure leading up to the oxygenation threshold that triggered the evolution of multicellular animals in the Ediacaran. Sequence 1 is composed of Marinoan glacial deposits and an overlying cap carbonate with aragonite fan pseudomorphs and barite. Sequence 2 is composed of lime-mudstone that changes laterally into loess-rich peritidal phosphorites, suggesting oxygen stratification in shallow paleoenvironments. Sequence 3 is a carbonate succession with abundant stromatolites implying widespread oxygen production. The top of Sequence 3 is marked by a regional subaerial unconformity developed during uplift associated with the onset of the Brasiliano-Pan African Orogeny. Sequence 4 signals a return to loess derived sedimentation. Distal deposits contain abundant organic matter with framboidal pyrite reflecting bacterial sulfate reduction in low sulfate Ediacaran seawater. Sequence 5 is composed of well-developed aggradational parasequences composed of alternating deep subtidal organic-rich siltstones and shallow-water carbonate grainstones. Their well-defined cyclicity is interpreted to record extreme sea level fluctuations during the onset of the Gaskiers glaciation. Stromatolites suggest an oxygen-stratified water column. Sequence 6 marks the change from an epeiric sea to a foreland basin. Interbedded basinal glauconitic siltstone and shale loess-rich are correlative with shoreface sandstones. Authigenic glauconite requires suboxic bottom waters to precipitate and thus reflects oxygenation of distal settings. Most of the deposition ended by ca. 560–550 Ma when the entire Bambui Group was deformed during the assembly of West Gondwana. In sequences 1, 2, 3, 4, 5, and the lower portion of 6, the lateral continuity of lithofacies, predictable layer-cake stratigraphy, and lack of fluvial coarse siliciclastic deposits are characteristics of epeiric sea successions. The appearance of immature sandstone, poorly sorted conglomerate, braided fluvial deposits, and synsedimentary deformation in the upper part of Sequence 6 are interpreted as the onset of foreland basin development. Stacking relationships of redox sensitive, authigenic lithofacies in both the epeiric sea and foreland phases support recent research suggesting seawater redox conditions were in a state of flux during the apex of the purported Neoproterozoic Oxygenation Event. Organic matter and authigenic pyrite in Sequences 4 and 5 reflect increased primary productivity in surface waters fertilized by nutrients such as P and Fe adsorbed on loess particles. This mechanism could be expanded to a global scale and have contributed to the increase in atmospheric and oceanic oxygen levels. These findings redefine and highlight the significance of the Bambui Group for Neoproterozoic Earth history. [ABSTRACT FROM AUTHOR]