Novel peapod-like Ni2P@N-doped carbon nanorods array on carbon fiber for efficient electrocatalytic urea oxidation and hydrogen evolution reaction.

Designing and optimizing structure is an effective method to enhance electrocatalytic performance of transition metal-based catalysts. In this work, an innovative nanostructured electrode, consisted of peapod-like Ni 2 P@N-doped carbon nanorods array coating on carbon fiber (CF@p-Ni 2 P@NC), is devised and synthesized. The N-doped carbon layer is crucial for maintaining the peapod-like nanostructure, which allows for multi-channel electrolyte transport and gas product release. And the carbon layer coating Ni 2 P nanoparticles also enhance electrical conductivity and stability, thus ensuring fast electron transport from/to active sites and the long-term stability of catalyst during urea oxidation reaction (UOR)/hydrogen evolution reaction (HER). Benefit from the reasonable structure, CF@p-Ni 2 P@NC present perfect performance with getting 100 mA cm−2 at potential/overpotential of 1.417/0.194 V for UOR/HER in 1.0 M KOH containing 0.5 M urea. In addition, the overall urea-electrolysis system using CF@p-Ni 2 P@NC bifunctional electrode only requires 1.590 V to obtain 100 mA cm−2. Novel peapod-like Ni 2 P@N-doped carbon nanorods array on carbon fiber is prepared and exhibits perfect catalytic activity toward both UOR and HER in urea-assisted electrolytic water splitting. [Display omitted] • Peapod-like Ni 2 P@N-doped carbon nanorods array on CF is designed and synthesized. • The CF@p-Ni 2 P@NC exhibits perfect catalytic activity toward both UOR and HER. • The superior performance is ascribed to the peapod-like nanorods array structure. [ABSTRACT FROM AUTHOR]