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An Efficient and Convenient Approach for Synthesizing Iodohydrin and Iodoether from Aromatic Alkenes Using Hg(BF4)2.SiO2 and I2.
- Source :
-
Polycyclic Aromatic Compounds . 2022, Vol. 42 Issue 7, p3975-3983. 9p. - Publication Year :
- 2022
-
Abstract
- A new and simple method for synthesizing iodohydrins and iodoethers from aromatic alkenes is described. Iodohydrins and iodoether derivatives were prepared in excellent yield using Mercury(II) tetrafluoroborate (Hg(BF4)2.SiO2)/I2 in aqueous THF or alcohols (methanol, iso-propanol and tert-butanol). The reactions take place at room temperature, short reaction times, and high regioselectivity, following Markovnikov fashion. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKENES
*TETRAFLUOROBORATES
*MERCURY
*ISOBUTANOL
*METHANOL
*ALCOHOL
Subjects
Details
- Language :
- English
- ISSN :
- 10406638
- Volume :
- 42
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Polycyclic Aromatic Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 158860233
- Full Text :
- https://doi.org/10.1080/10406638.2021.1878247