Cerium-terephthalic acid metal-organic frameworks for ratiometric fluorescence detecting and scavenging·OH from fuel combustion gas.

Hydroxyl radical (•OH) in fuel combustion gas seriously damages human health. The techniques for simultaneously detecting and scavenging •OH in these gases are limited by poor thermal resistance. To meet this challenge, herein, metal organic frameworks (MOFs) with high thermal stability (80–400 °C) and dual function (•OH detection and elimination) are developed by coordinating Ce ions with terephthalic acid (TA) (Ce-BDC). Due to the reversible conversion between Ce3+ and Ce4+, and the high concentration of Ce3+ on the surface of Ce-BDC MOFs (89.6%), an •OH scavenging efficiency over 90% is realized. Ratiometric fluorescence (I 440 nm /I 355 nm) detection of •OH with a low detection limit of ∼4 μM is established by adopting Ce ions as an internal standard and TA as an •OH-responsive fluorophore. For real applications, the Ce-BDC MOFs demonstrate excellent •OH detection sensitivity and high •OH scavenging efficiency in gas produced from cigarettes, wood fiber and machine oil. Mouse model results show that the damage caused by •OH in cigarette smoke can be greatly reduced by Ce-BDC MOFs. This work provides a promising strategy for sensitively detecting and efficiently eliminating •OH in fuel combustion gas. [Display omitted] • Ce-BDC can realize ratiometric fluorescence detection of •OH at high temperature. • The reversible conversion between Ce3+ and Ce4+ make Ce-BDC high •OH removing effect. • Ce-BDC can simultaneously detect and eliminate •OH in high temperature gas. • Ce-BDC can modify cigarette to reduce hazard caused by •OH in cigarette smoke. [ABSTRACT FROM AUTHOR]