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Photocatalyzed difluoroalkylation of pyridine N-oxides.
- Source :
-
Synthetic Communications . 2022, Vol. 52 Issue 17, p1727-1741. 15p. 1 Illustration, 5 Diagrams, 3 Charts. - Publication Year :
- 2022
-
Abstract
- A photoredox catalytic strategy has been developed for the regioselective C2-, or C4-difluoroalkylation of pyridine N-oxides under mild conditions. This method provides an efficient protocol for the incorporation of electrophilic difluoroacetate radical (CF2CO2Et) into pyridine skeletons, based on the strategy of nitrogen-atom activation on electron-deficient pyridine moieties. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PYRIDINE
*MOIETIES (Chemistry)
*SKELETON
Subjects
Details
- Language :
- English
- ISSN :
- 00397911
- Volume :
- 52
- Issue :
- 17
- Database :
- Academic Search Index
- Journal :
- Synthetic Communications
- Publication Type :
- Academic Journal
- Accession number :
- 158997960
- Full Text :
- https://doi.org/10.1080/00397911.2022.2112057