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Rapid identification of the short-lived intermediates in alternating-current electrolysis by mass spectrometry.
- Source :
-
Chemical Communications . 9/18/2022, Vol. 58 Issue 73, p10233-10236. 4p. - Publication Year :
- 2022
-
Abstract
- Herein, we report the rapid mass spectrometric identification of the short-lived intermediates generated under AC electrolysis via combining bipolar electrochemistry with nanoelectrospray ionization in a hybrid ultramicroelectrode/ion emitter. The key reactive intermediates involved in the C–O/O–H cross-metathesis between 4-alkoxy anilines and alcohols were successfully captured and identified for the first time, providing direct evidence for the previously proposed mechanism. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 58
- Issue :
- 73
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 159098762
- Full Text :
- https://doi.org/10.1039/d2cc04363g