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Hydrolysis of a carbamate triggered by coordination of metal ions.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 9/14/2022, Vol. 51 Issue 34, p12915-12920. 6p. - Publication Year :
- 2022
-
Abstract
- The mechanism of carbamate activation promoted by different metal ions has been explored in this work. The reaction of the carbamate ligand H2L with chloride metal salts (M = Ni, Cu, Zn, Cd) leads to the coordination of the metal ions to the ligand, causing hydrolysis of the systems. This self-immolation process results in mononuclear dihydrazone complexes, carbon dioxide and the release of alcohol species from the pendant groups of the carbamate ligand. The conditions under which this process occurs have been studied in detail. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 51
- Issue :
- 34
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 159231299
- Full Text :
- https://doi.org/10.1039/d2dt01622b