Nitrogen-rich triazine-based porous polymers for efficient removal of bisphenol micropollutants.

Achieving both rapid adsorption rate and high adsorption capacity for bisphenol micropollutants from aquatic systems is critical for efficient adsorbents in water remediation. Here, we elaborately prepared three nitrogen-rich triazine-based porous polymers (NTPs) with similar geometric configurations and nitrogen contents (41.70–44.18 wt%) while tunable BET surface areas and micropore volumes in the range of 454.7–536.3 m2 g−1 and 0.20–0.84 cm3 g−1, respectively. It was systematically revealed that the synergy of hydrogen bonding, π−π electron-donor-acceptor interaction, and micropore preservation promoted the rapid (within 5 min) and high capacity adsorption of bisphenols by NTPs. Particularly, microporous-dominated NTPs-3 with the highest micro-pore volume (0.84 cm3 g−1) displays remarkable adsorption capacity towards bisphenol A as evidenced by the adsorption capacity of 182.23 mg g−1. A simple column filter constructed by NTPs-3 also expressed good dynamic adsorption and regeneration capacity. This work provided new insight into the rational design and engineering of nitrogen-rich porous polymers for the remediation of micropollutant wastewater. Three nitrogen-rich triazine-based porous polymers with similar geometric configurations and nitrogen contents while tunable BET surface areas and micropore volumes were used for the adsorption of bisphenol micropollutants. [Display omitted] • NTPs have similar geometric configurations and nitrogen contents while tunable porosities. • The adsorption mechanism is the synergy of hydrogen bonding, π−π interaction, and micropore preservation. • NTPs-3 expressed rapid and high capacity adsorption of bisphenols. • A simple column filter constructed by NTPs expressed good dynamic adsorption and regeneration capacity. [ABSTRACT FROM AUTHOR]