Polyethylenimine grafted ZIF-8@cellulose acetate membrane for enhanced gas separation.

Mixed matrix membranes (MMMs) combine the advantages of both polymers and inorganic fillers, and hold great promise for industrial gas separation. In this work, to enhance the interfacial compatibility between cellulose acetate (CA) matrix and ZIF-8 crystals, an interfacial design strategy was proposed by grafting polyethylenimine (PEI) onto ZIF-8 particles. The introduction of amine-rich PEI could regulate the surface property and maintain the pore accessibility of ZIF-8 crystals. In addition, the amine groups in PEI could interact with hydroxyl/carbonyl groups in CA chains to suppress the non-ideal voids at the ZIF-8/CA interface. With the aid of PEI, the interfacial compatibility between ZIF-8 and CA is substantially enhanced. Compared with pristine CA and ZIF-8@CA membranes, PEI grafted ZIF-8@CA (PZIF-8@CA) membrane exhibits a better gas separation performance, bearing a CO 2 permeability of 150.3 Barrer with CO 2 /N 2 and CO 2 /CH 4 ideal selectivities of 44.2 and 53.7, respectively. The separation mechanisms are attributed to the superior interfacial property, the good dispersion of ZIF-8 particles, the amine groups in PEI, and the high CO 2 solubility of the CA matrix. [Display omitted] • PEI grafted ZIF-8 (PZIF-8) is introduced into cellulose acetate to obtain MMMs. • PEI boosts the interfacial compatibility between ZIF-8 and cellulose acetate. • The optimal PZIF-8/CA membrane has a CO 2 permeability of 150.3 Barrer. • The membrane has CO 2 /N 2 and CO 2 /CH 4 ideal selectivities of 44.2 and 53.7 [ABSTRACT FROM AUTHOR]