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Pd‐Catalyzed MIA‐Directed Acetoxylation of Benzylamines and Computational Study.
- Source :
-
European Journal of Organic Chemistry . 10/7/2022, Vol. 2022 Issue 37, p1-5. 5p. - Publication Year :
- 2022
-
Abstract
- The direct acetoxylation of substituted benzylamines has been accomplished through methoxyiminoacyl (MIA)‐mediated Pd‐catalyzed C−H functionalization. A diverse array of phenylalanine substrates is amenable to this protocol, providing acetoxylation benzylamine derivatives with good to high efficiency. Computational results revealed that HOAc enhanced the stability of Pd−O bond, which obviously accelerate the reductive elimination step of the acetoxylation process. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BENZYLAMINES
*BENZYLAMINE
*PHENYLALANINE
Subjects
Details
- Language :
- English
- ISSN :
- 1434193X
- Volume :
- 2022
- Issue :
- 37
- Database :
- Academic Search Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 159615047
- Full Text :
- https://doi.org/10.1002/ejoc.202200728