Thiourea crosslinked-amino modified graphene nanoflakes as an effective adsorbent to confine Cr(VI) via multiple combination mechanisms.

The high pathogenicity to organisms and high destructiveness in the natural environment determine the utmost importance of removing Cr(VI) from water. Herein, thiourea crosslinked-amino modified graphene nanoflakes (TAGN) was prepared by simple ring opening reaction and silanization reaction and the Cr(VI) adsorption performance was investigated. Results manifested that TAGN presented three-dimensional porous structure with abundant folds and avoided agglomeration. The adsorption experiments indicated that the optimal test pH value was 2 and the most suitable adsorbent dosage was 1 g/L. Under the optimum adsorption conditions, TAGN exhibited an outstanding adsorption capacity of 193.77 mg/g for Cr(VI) in water. Various characterizations and tests such as Zeta potential, FTIR, XPS as well as isotherms and kinetics revealed that the adsorption of TAGN for Cr(VI) was more consistent with Freundlich isotherm model and pseudo-second-order kinetic model, confirming a multilayer chemisorption process dominated by multiple combination mechanisms: electrostatic interaction, reduction reaction, complexation and hydrogen bonding interaction. Under the condition of coexistence of multiple metal ions, the TAGN could still maintain superb selectivity of 63.9% towards Cr(VI). After ten cycling test, 81.8% removal efficiency of Cr(VI) was guaranteed. Therefore, TAGN possessed high adsorption capacity, excellent selectivity and prominent cyclic regeneration ability. This work provided a promising nanosorbent for the field of water cleaning, especially for the elimination of heavy metal ions. [Display omitted] • Thiourea crosslinked-amino modified graphene nanoflakes were fabricated via simple ring opening reactions and silanation reactions. •The adsorbent presented three-dimensional porous structure with abundant folds and avoided agglomeration. •The adsorbent displayed outstanding purification efficiency towards Cr(VI). •Superior selectivity in highly concentrated polymetallic solutions was achieved. •Remarkable stability in the cyclic test was obtained for the neoteric sorbent. [ABSTRACT FROM AUTHOR]