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Building Metal‐Molecule Interface towards Stable and Reversible Zn Metal Anodes for Aqueous Rechargeable Zinc Batteries.
- Source :
-
Advanced Functional Materials . 11/17/2022, Vol. 32 Issue 47, p1-11. 11p. - Publication Year :
- 2022
-
Abstract
- Aqueous zinc ion batteries (AZIBs) are receiving increasing attention for large‐scale energy storage systems owing to their appealing features with intrinsic safety, low cost, and scalability. Unfortunately, the water‐induced parasitic reactions and dendrite growth on the Zn anode severely impede the further development of AZIBs. Herein, a thiourea additive is introduced into ZnSO4 electrolyte to construct unique metal‐molecule interface for simultaneously regulating the Zn anode interface chemistry and the bulk electrolyte environment. Experimental results and theoretical calculations reveal that the formed metal‐molecule interface can not only serve as a corrosion inhibitor for alleviating the water‐induced side reactions, but also act as a Zn2+ ion regulator for promoting the homogenous Zn deposition, thus achieving a corrosion‐free and dendrite‐free Zn anode. Consequently, the Zn|Zn symmetric cell exhibits an extended lifespan of 1200 h at 1 mA cm–2, 1mAh cm–2, and a high cumulative capacity of 3000 mAh cm–2 at 10 mA cm–2. When paired with V2O5 cathode, the Zn|V2O5 full cell delivers a high capacity retention of 76.0% after 1000 cycles at 1 A g–1. This study paves a new way to modulate Zn electrode interface chemistry by the novel design of metal‐molecule interface for advanced rechargeable Zn metal batteries and beyond. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ENERGY storage
*ANODES
*STORAGE batteries
*SURFACE chemistry
*ZINC ions
*METALS
Subjects
Details
- Language :
- English
- ISSN :
- 1616301X
- Volume :
- 32
- Issue :
- 47
- Database :
- Academic Search Index
- Journal :
- Advanced Functional Materials
- Publication Type :
- Academic Journal
- Accession number :
- 160306553
- Full Text :
- https://doi.org/10.1002/adfm.202206695