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Direct Synthesis of 3‐Aryl Substituted Isocoumarins and Phthalides through Palladium Acetate Catalyzed C(sp2)−H Activation in Ionic Liquids.
- Source :
-
Chemistry - A European Journal . Nov2022, Vol. 28 Issue 65, p1-6. 6p. - Publication Year :
- 2022
-
Abstract
- A novel Pd‐catalysed oxidative coupling between benzoic acids and vinylarenes or acrylates to furnish isocoumarins and phthalides is reported. The reaction proceeds smoothly in molten tetrabutylammonium acetate via a selective C−H bond activation, with very low percentage of ligand‐free palladium acetate as the catalyst, under atmospheric pressure of oxygen. Sub‐stoichiometric amount of copper acetate is also required as a reoxidant for the palladium. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 28
- Issue :
- 65
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 160328960
- Full Text :
- https://doi.org/10.1002/chem.202202350