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Atomic-scale interfacial engineering enables high-performance electrochemical glucose detection.
- Source :
-
Applied Surface Science . Feb2023, Vol. 610, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- [Display omitted] • Atomic layer deposition was adapted to deposit Co 9 S 8 on the Ni(OH) 2 nanosheets, which were then in-situ activated to form Ni@Co hetero-structured electrodes. • The Ni@Co heterostructure exhibited strongly promoted glucose detection performance. • The changes in the local electronic structure and the promoted deprotonation process near the heterointerface contributed to the high detection performance. Developing noble-metal free electrocatalysts with high sensitivity is critical for the large-scale application of electrochemical glucose sensors. This work reports an atomic-scale interfacial engineering strategy to construct highly-active electrocatalyst for glucose detection. Ni(OH) 2 nanosheets are decorated with an ultra-thin layer of Co 9 S 8 using the atomic layer deposition (ALD) technique. After in-situ reconstruction, we obtain Ni@Co heterostructure composed of Ni hydroxide nanosheets and CoO x clusters, which exhibits outstanding electrochemical glucose sensing performance. Combining synchrotron-based X-ray adsorption spectroscopy, in situ Raman Spectroscopy, intermittent electrochemical measurements and density functional theory (DFT) calculations, we find that the presence of surface CoO x not only lowers the valence state of Ni, but also facilitates the deprotonation of Ni(OH) 2 to form NiOOH active species for glucose oxidation. The approach used in this work can be adapted to synthesizing high-performance electrocatalysts for other energy and environmental devices. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01694332
- Volume :
- 610
- Database :
- Academic Search Index
- Journal :
- Applied Surface Science
- Publication Type :
- Academic Journal
- Accession number :
- 160364714
- Full Text :
- https://doi.org/10.1016/j.apsusc.2022.155503