Allomorphic regulation of bamboo cellulose by mild alkaline peroxide for holocellulose nanofibrils production.

The exploration of sustainable lignocellulosic nanomaterials with unique properties and applicable functions is receiving growing interest. In this work, holocellulose nanofibrils (HCNFs) were prepared from moso bamboo using mild alkaline peroxide bleaching method (MAPB) followed by mechanical nanofibrillation. MAPB was proved to effectively remove lignin and retain hemicellulose. Meanwhile, partial allomorphic changes from cellulose I to cellulose II were revealed together with varying degrees of crystallinity. Thermogravimetric analysis (TGA) experiment showed an increasing thermal stability trend due to more allomorphic changes into anti-parallel cellulose II. Well-dispersed HCNFs suspensions were successfully prepared by homogenization and HCNFs films with high transparency and flexibility were fabricated. The films reached the maximum tensile strength of 55.8 MPa and tensile strain of 1.55 % along with a calculated toughness of 25 MJ/m3. Moreover, the prepared materials are biocompatible and completely non-toxic, which will theoretically support the application of HCNFs materials in fields of biology, medicine and food industry. [Display omitted] [ABSTRACT FROM AUTHOR]