Back to Search
Start Over
Methylene blue adsorption in DUT-5: Relatively strong host-guest interactions elucidated by FTIR, solid-state NMR, and XPS.
- Source :
-
Journal of Molecular Liquids . Dec2022:Part B, Vol. 368, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- [Display omitted] • DUT-5 for water remediation with notable chemical stability and cyclability. • High adsorption capacity and stability at different pH with fast MB adsorption. • Strong host-guest interactions by cooperative and different physicochemical interactions. • Presence of π-π stacking, cation-π interactions, and hydrogen bonds. The existence of dyes in water causes environmental and health problems. Thus, a Metal-Organic Framework entitled DUT-5 was explored in the methylene blue adsorption process. DUT-5 showed a high adsorption performance exhibiting a maximum adsorption capacity of 140.66 mg g−1 in a short contact time of 45 min and stability at different pHs from 4 to 8. The adsorption isotherms and kinetic data followed the Temkin and PSO models, respectively, which suggested the involvement of physico-chemical forces in the adsorption process. The thermodynamic study confirmed the exothermic nature of the process. The key to the high adsorption of MB was the relatively strong host-guest interactions by cooperative and different physicochemical interactions, which were elucidated by FTIR, solid-state NMR, and XPS. Moreover, DUT-5 proved to be an exceptional candidate for methylene blue remediation with remarkable chemical stability and cyclability. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01677322
- Volume :
- 368
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Liquids
- Publication Type :
- Academic Journal
- Accession number :
- 160582262
- Full Text :
- https://doi.org/10.1016/j.molliq.2022.120758