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High-temperature ultrafast welding creating favorable V2O5 and conductive agents interface for high specific energy thermal batteries.
- Source :
-
Ceramics International . Jan2023, Vol. 49 Issue 2, p1791-1799. 9p. - Publication Year :
- 2023
-
Abstract
- The high interfacial resistance between V 2 O 5 cathode materials and conductive agents (molten salt and super carbon) is one of the biggest issues that hinder the development of high specific energy thermal batteries. Designing fast Li+ and e– transport channels in cathode electrodes is considered as an effect method to improve electrochemical performance. Hence, a high-temperature ultrafast welding is proposed to reduce V 2 O 5 /conductive agents interfacial resistance by reconstructing the transmission channels of Li+ and e– in this paper. The experimental studies reveal the optimum ultrafast welding of 700 °C for 10 s, eliminating gap resistance of cathode electrodes induced by the melt of solid molten salt and rebuilding the more plentiful Li+ and e– transport channels, further reducing the contact resistance and gap resistance. Therefore, the electrodes deliver a high specific capacity of 270.69 mAh g−1 and a high specific energy of 610.60 Wh kg−1 at 0.1 A cm−2 and 500 °C with a cut-off voltage of 1.6 V. The high-temperature ultrafast welding provides guidance to build Li+ and e– transport channels of other cathode materials in thermal batteries. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 49
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 160692224
- Full Text :
- https://doi.org/10.1016/j.ceramint.2022.09.142