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B-value definition in Galvele's pit model.
- Source :
-
Corrosion Science . Feb2023, Vol. 211, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- We use one-dimensional mass transport models to investigate the chloride concentration effect on the potential drop inside a pit cavity. Galvele's pitting model predicts a B value of 59 mV, independent of the complexation reactions and concentration-dependent diffusivity when ions can migrate freely. Higher B values (>59 mV) at 25 °C are commonly attributed to ion interactions in the pit solution, also explaining the material and electrolyte effect on the B value in Galvele's pit model. Our analysis suggests that practical pitting corrosion models require a comprehensive mass transport component that includes multi-species interactions. [ABSTRACT FROM AUTHOR]
- Subjects :
- *COMPLEXATION reactions
*PITTING corrosion
*DEFINITIONS
Subjects
Details
- Language :
- English
- ISSN :
- 0010938X
- Volume :
- 211
- Database :
- Academic Search Index
- Journal :
- Corrosion Science
- Publication Type :
- Academic Journal
- Accession number :
- 161059873
- Full Text :
- https://doi.org/10.1016/j.corsci.2022.110906