Site‐selective multi‐emitter gold‐silver metallopolymers: A novel class of self‐assembled materials.

New luminescent heterometallopolymers [(Au‐C6F5)m(AgOSO2CF3)n (PVP)] with different Au:Ag molar ratios were synthesized. The luminescent emissions of these polymers are strongly dependent on the temperature, excitation wavelengths, and the Au(I):Ag(I) molar ratio. The incorporation of a precise amount of Ag(I) atoms in the backbone of [(Au‐C6F5)m(PVP)] metallopolymer allows a controlled tuning of the emission energy in the green‐blue range. [ABSTRACT FROM AUTHOR]