Efficient preparation of ultrathin ceramic wafer membranes for the high-effective treatment of the oilfield produced water.

[Display omitted] • A thin ceramic wafer was fabricated via an efficient phase inversion/sintering. • The thickness of the ceramic wafer was 250 μm with a mean pore size of 200 nm. • The high Al 2 O 3 loading helps their uniform distribution on membrane surface. • This wafer exhibited an ultrahigh and stable flux and oil removal efficiency. • The fouling analysis shows the dominant fouling mechanism was cake filtration. Efficient preparation of ceramic membranes helps to reduce costs and makes them more competitive in the field of wastewater treatment. In this work, an ultrathin Al 2 O 3 ceramic wafer membrane with a thickness of 250 µm and the mean pore size of approximately 200 nm was prepared from the Al 2 O 3 /polysulfone slurries via a casting-phase inversion/sintering approach. This ultrathin and hydrophilic ceramic wafer has a fully sponge-like and slightly asymmetric structure and desirable porosity, endowing it with an exceptionally high pure water permeability of ∼ 45,000 L m-2h−1 bar−1, an ultrahigh and stable emulsion flux of 2500 ∼ 3500 L m-2h−1 bar−1, as well as a high oil rejection of 99 % against real oilfield produced water (OPW). In addition, the increased Al 2 O 3 content enhanced the thermodynamic instability of the ceramic slurry, leading to the enhanced interfacial instability, which contributes to the uniform distribution of Al 2 O 3 particles on the precursor membrane surface to some extent during the phase inversion process, thus to reduce the surface defects of ceramic membranes after sintering. The membrane fouling analysis revealed that the dominant fouling mechanism was cake filtration, indicating the formation of a relatively dense and smooth skin layer of the ceramic wafer, which endow it with a high flux recovery ratio of 97.8 % by a simple chemical cleaning after OPW filtration. [ABSTRACT FROM AUTHOR]