Dual-metal hydroxide@oxide heterojunction catalyst constructed via corrosion engineering for large-current oxygen evolution reaction.

Current OER electrocatalysts are hardly applicable for industrial use, which demands high current density (≥ 1000 mA cm-2) at low overpotential (≤ 300 mV) with long-term stability (≥ 100 h). Herein self-supported heterojunction catalyst, NiCo-OH@Ni x Fe y O 4 on Fe foam (FF), is in situ synthesized using two-step corrosion engineering. It only requires an overpotential 275 mV to drive the current density of 1000 mA cm-2 with good long-term stability. Theoretical calculations reveal that such good performance is attributable to electron transfer from NiCo-OH to Ni x Fe y O 4 which weakens the adsorption energy of reaction intermediate (OOH*) to promote the release of O 2 and lowers the free energy barriers for the reaction. Furthermore, a water splitting cell with NiCo-OH@Ni x Fe y O 4 /FF as anode and CoP@FeP/FF as cathode demonstrates its potential for industrial application. The study presents a general strategy for in situ synthesis of heterojunction catalysts on metal foams using controlled corrosion engineering for various catalytic applications. [Display omitted] • NiCo-OH@Ni x Fe y O 4 heterojunction in situ grown on Fe Foam by corrosion engineering. • NiCo-OH@Ni x Fe y O 4 /FF shows great OER activity (j 1000 =275 mV) with long-term stability. • Regulated d-band center of metal site optimizes binding energy of intermediates. • DFT confirms lower ∆G of rate-determined step due to charge transfer at interface. • NiCo-OH@Ni x Fe y O 4 /FF is an excellent anode for industrial water splitting. [ABSTRACT FROM AUTHOR]