CFD-DEM study of reactive gas-solid flows with cohesive particles in a high temperature polymerization fluidized bed.

• The cohesive gas–solid flows coupled with a polymerization reaction are simulated. • The effect of cohesion on hydrodynamic and thermal behaviors is quantified. • The formation of hot spots in the agglomerates is detailed analyzed. • How the cohesion model parameters affect the particle agglomeration is revealed. The cohesive particles are commonly encountered in high temperature polymerization fluidized bed reactors. However, detailed studies on the effect of cohesiveness on the hydrodynamics, heat transfer, and reaction characteristics in such reactors have been rarely reported. In this work, a CFD-DEM approach coupled with solid bridge force model and polymerization reaction kinetics model is established to simulate the reactive gas–solid flows with cohesive particles. The results demonstrate that cohesive particle agglomeration significantly increases the inhomogeneity of concentration and velocity fields, and hinders particle circulation. The hindered particle circulation further results in pronounced temperature inhomogeneity. Moreover, the local hot spots are readily formed in the agglomerates, which expand and deteriorate rapidly if not controlled promptly. Besides, how the cohesion model parameters, namely contact time and maximum cohesive force limitation, affect the onset temperature and the severity of particle agglomeration is revealed. The established model extends the particle-scale study of cohesive gas–solid flows to reactive systems. [ABSTRACT FROM AUTHOR]