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A Zr-added Dawson-type poly(polyoxometalate).
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 1/28/2023, Vol. 52 Issue 4, p857-861. 5p. - Publication Year :
- 2023
-
Abstract
- A novel Zr-added trimer, [H2N(CH3)2]10H14[(Zr2P2W16O61)3]·7H2O (1), has been made under hydrothermal conditions, and contains the highest number of Zr centers in known Dawson-type poly(POM)s. A remarkable feature of this study is the first discovery of a new type of divacant [α-5,10-P2W16O60]14− fragment, which assembles with Zr4+ ions to form a cyclic trimer. Furthermore, 1 as a heterogeneous catalyst exhibits high activity for the selective oxidative degradation of a sulfur mustard simulant CEES. [ABSTRACT FROM AUTHOR]
- Subjects :
- *MUSTARD gas
*HETEROGENEOUS catalysts
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 52
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 161481306
- Full Text :
- https://doi.org/10.1039/d2dt03820j