Pt-O-Cu anchored on Fe2O3 boosting electrochemical water-gas shift reaction for highly efficient H2 generation.

[Display omitted] • The unique Pt-O-Cu structure is constructed on the 2.5Pt-2Cu/Fe 2 O 3 catalyst. • The Pt-O-Cu site shows the best reactivity for EWGS reaction. • The Pt-O-Cu site balances the binding ability of CO and the activation of OH–. • The Pt-O-Cu structure greatly boots the capability in antioxidation of Pt. Electrochemical water–gas shift (EWGS) reaction is an emerging technology with energy-saving and environmental-friendly advantages to produce high-purity hydrogen form the waste gas containing CO. However, it remains a significant challenge to design superior activity and highly durable EWGS electrocatalysts, particularly with low content of noble metals. Herein, a series of Pt-xCu/Fe 2 O 3 (x = 0, 2, 5) catalysts are synthesized by the complexation precipitation method to construct coupling sites between Pt and CuOx, aiming to optimize the adsorption of CO and the activation of OH–. The obtained 2.5Pt-2Cu/Fe 2 O 3 catalyst presents a unique Pt-O-Cu structure, delivering a much lowest onset potential, high specific activity, and excellent mass activity (1.5 A·mg Pt -1) at 0.73 V (vs. RHE), which is over 15 and 3 times that of commercial Pt/C (20%) and unmodified Pt/Fe 2 O 3 catalyst, respectively. Meanwhile, the in-situ X-ray absorption results demonstrate that the facilitated interaction among the Pt-O-Cu structure promotes the high durability of the 2.5Pt-2Cu/Fe 2 O 3 catalyst and the operability at high potential. More importantly, the moderate binding of CO and moderate activation of OH* are suggested for boosting the reactivity in the CO electro-oxidation reaction. In particular, the fabricated Pt||2.5Pt-2Cu/Fe 2 O 3 , employed in coupling the HER and CO electro-oxide reaction, shows a remarkable hydrogen production of about 98 mmol H2 ·h−1·mg Pt −1 at 0.8 V (vs. RHE). This work also definitely confirms the possibility of the catalyst being applied to produce hydrogen under practical conditions with different concentrations of CO, even being applied in the purification of trace CO in a hydrogen-rich atmosphere. [ABSTRACT FROM AUTHOR]