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Monitoring Transformations of Catalytic Active States in Photocathodes Based on MoSx Layers on CuInS2 Using In Operando Raman Spectroscopy.
- Source :
-
Angewandte Chemie . 2/6/2023, Vol. 135 Issue 7, p1-6. 6p. - Publication Year :
- 2023
-
Abstract
- The electrochemical activation of CuInS2/MoSx for photoelectrochemical (PEC) H2 production was revealed for the first time through in operando Raman spectroscopy. During the activation process, the initial metallic MoSx phase was transformed to semiconducting MoSx, which facilitates charge carrier transfer between CuInS2 and MoSx. Ex situ X‐ray photoelectron spectroscopy and Raman spectroscopy suggest the existence of MoO3 after the activation process. However, apart from contradicting these results, in operando Raman spectroscopy revealed some of the intermediate steps of the activation process. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 135
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 161691305
- Full Text :
- https://doi.org/10.1002/ange.202215227