Back to Search
Start Over
Phase transition and energy storage properties of Bi0.5Na0.5TiO3–Bi(Mg2/3Nb1/3)O3 lead-free ceramics.
- Source :
-
Ceramics International . Mar2023, Vol. 49 Issue 6, p9615-9621. 7p. - Publication Year :
- 2023
-
Abstract
- Bi 0.5 Na 0.5 TiO 3 (BNT) lead-free ceramics have been extensively studied due to their excellent dielectric, piezoelectric and ferroelectric properties. The phase structure and functionalities of BNT can be feasibly adjusted by doping/forming solid solutions with other elements/components. In this work, Bi(Mg 2/3 Nb 1/3)O 3 (BMN) was introduced into BNT by a conventional solid-state reaction to form a homogeneous solid solution of (1-x)(Bi 0.5 Na 0.5)TiO 3 -xBi(Mg 2/3 Nb 1/3)O 3 (BNT-xBMN) with a perovskite structure. With the increase of BMN content, a phase transition from rhombohedral R3c to tetragonal P4bm has been confirmed by XRD, along with shifting the ferroelectric-paraelectric phase transition temperature to lower temperatures with broadening dielectric peaks. Furthermore, an optimized recoverable energy density of 1.405 J/cm3 was achieved for BNT-0.10BMN ceramics under a low applied electric field of 140 kV/cm, which is mainly attributed to the transformation from ferroelectric to ergodic relaxor phase. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 49
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 161818297
- Full Text :
- https://doi.org/10.1016/j.ceramint.2022.11.131