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Synthesis and characterization of 4-chlorobutyl ester of 5-(8-carboxyl-1-naphthyl)-10,15,20-triphenyl-porphyrin and its zinc complex.
- Source :
-
Inorganic & Nano-Metal Chemistry . 2017, Vol. 47 Issue 4, p597-602. 6p. - Publication Year :
- 2017
-
Abstract
- In the presence of Brønsted–Lowry acids (phenol or dry HCl), the acyl chloride, which was obtained by the reaction between 5-(8-carboxyl-1-naphthyl)-10,15,20-triphenyl-porphyrin (CNTPP) and oxalyl chloride, reacted with tetrahydrofuran and led to the 4-chlorobutyl ester, P1, as the result of the acylative cleavage. P1 and its zinc complex [ZnP1] have been characterized by 1H NMR. The structure of [ZnP1] was obtained by X-ray crystallography. Zinc is coordinated by four pyrrole nitrogens. The 8-position substituent, a 4-chlorobutyl ester group, lies above the porphyrin plane. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 24701556
- Volume :
- 47
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Inorganic & Nano-Metal Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 162079924
- Full Text :
- https://doi.org/10.1080/15533174.2016.1212214