Carbon Quantum Dots: Synthesis, Structure, Properties, and Catalytic Applications for Organic Synthesis.

Carbon quantum dots (CQDs), also known as carbon dots (CDs), are novel zero-dimensional fluorescent carbon-based nanomaterials. CQDs have attracted enormous attention around the world because of their excellent optical properties as well as water solubility, biocompatibility, low toxicity, eco-friendliness, and simple synthesis routes. CQDs have numerous applications in bioimaging, biosensing, chemical sensing, nanomedicine, solar cells, drug delivery, and light-emitting diodes. In this review paper, the structure of CQDs, their physical and chemical properties, their synthesis approach, and their application as a catalyst in the synthesis of multisubstituted 4H pyran, in azide-alkyne cycloadditions, in the degradation of levofloxacin, in the selective oxidation of alcohols to aldehydes, in the removal of Rhodamine B, as H-bond catalysis in Aldol condensations, in cyclohexane oxidation, in intrinsic peroxidase-mimetic enzyme activity, in the selective oxidation of amines and alcohols, and in the ring opening of epoxides are discussed. Finally, we also discuss the future challenges in this research field. We hope this review paper will open a new channel for the application of CQDs as a catalyst in organic synthesis. [ABSTRACT FROM AUTHOR]