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An improved method of MgFe-layered double hydroxide/ biochar composite synthesis.
- Source :
-
Journal of Cleaner Production . Mar2023, Vol. 393, pN.PAG-N.PAG. 1p. - Publication Year :
- 2023
-
Abstract
- Layered double hydroxides (LDHs) and their composites are a promising platform for a wide range of applications, especially in the environmental field. However, the facile and efficient synthesis of high-quality LDHs and their composites remains a challenge. Here, an improved co-pyrolysis method has been developed to synthesize LDH/biochar composites. A composite material was prepared by directly anchoring MgFe-LDH on corn stover by co-precipitation with FeCl 3 and Mg(OH) 2 , and then through pyrolysis. The main features of this improved method are the use of the solubility product Mg(OH) 2 to maintain the pH of the mixture at ∼10 (the optimum for LDH precipitation), eliminating the cumbersome pH control steps of the traditional co-precipitation method, and the low rate of solid-liquid reaction to obtain high LDH crystallinity and purity. This produces improved properties of the MgFe-LDH/biochar composite after pyrolysis: higher loading of MgFe-LDH, larger specific surface area of the composite, a more stable layered structure, and a more customizable LDH. The theoretical maximum adsorption capacity of phosphorus for the composite was 379.4 mg L−1 according to an adsorption isotherm study, and the dominant adsorption mechanism is chemical adsorption accompanied by physical adsorption. In actual wastewater applications, >80% of total phosphorus in biogas slurry was removed via adsorption, indicating that the composite is highly efficient in phosphorus selectivity in wastewaters with complex components. Here, a more sustainable synthesis method of LDH/biochar composite has been developed with high application potential. [Display omitted] • A facile innovative method for the synthesis of MgFe-LDH/biochar composites is proposed. • Mg(OH) 2 was used to spontaneously adjust the co-precipitation pH. • MgFe-LDH anchored on biomass using the new method has higher crystallinity and purity. • The derived MgFe-LDH/biochar exhibits an excellent phosphorus removal capability. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09596526
- Volume :
- 393
- Database :
- Academic Search Index
- Journal :
- Journal of Cleaner Production
- Publication Type :
- Academic Journal
- Accession number :
- 162091768
- Full Text :
- https://doi.org/10.1016/j.jclepro.2023.136186