The molecular mechanisms of plasticizers in rejuvenating oxidized asphalt: A preliminary study.

[Display omitted] • The plasticizers of DBP and TBC effectively restored the stiffness, relaxation capability, and crack resistance of the aged asphalt. • Both plasticizers lowered the glass transition temperature and broadened the transition region and linear viscoelastic relaxation spectrum. • TBC exhibited a stronger deagglomerating effect based on analytical characterizations and molecular dynamics simulations. • The higher rejuvenating effectiveness of TBC was due to its higher polarity and forming hydrogen bonds with asphalt molecules. Plasticizers are common additives used to enhance the flexibility and workability of polymer materials. Recent findings suggest a great potential for typical plasticizers being used as rejuvenators to recycle oxidized paving asphalts. This study investigated the rejuvenating effectiveness of two plasticizers via rheological evaluation and explored the underlying mechanism by analytical characterizations and molecular dynamics (MD) simulations. A conventional plasticizer dibutyl phthalate (DBP) and an environmentally friendly tributyl citrate (TBC) were selected given the discrepancies in their molecular structures. Both plasticizers were effective in restoring the rheological performance of the aged asphalt; TBC was relatively more efficient which was attributed to its higher molecular polarity and the formation of hydrogen bonds with the oxidized asphalt molecules. Analyses based on the gel permeation chromatography and differential scanning calorimetry suggested the capability of the plasticizers in dissociating the oxidized asphalt molecules and improving the molecular mobility. The improved molecular mobility was considered responsible for the reversing effect of the plasticizers, as compared to aging, in terms of widening the relaxation spectrum and broadening the glass transition region. The plasticizers' dissociating effect was confirmed and visualized in the simulations by inspecting their impacts on the spatial arrangement and distribution of the asphaltenes. [ABSTRACT FROM AUTHOR]