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Graphene aerogel encapsulated Co3O4 microcubes derived from prussian blue analog as integrated anode with enhanced Li-ion storage properties.
- Source :
-
Ceramics International . Apr2023, Vol. 49 Issue 8, p11788-11795. 8p. - Publication Year :
- 2023
-
Abstract
- In lithium-ion batteries (LIB), cobalt oxide is considered an ideal anode material because of its theoretical specific capacity of up to 890 mAh g−1, abundant resources, and low price. However, the volume expansion during the charging and discharging process and its lower conductivity have hindered its development. In this work, a metal-organic framework (MOF) was used as an initial template, encapsulated in graphene aerogels (GA) by hydrothermal and programmed temperature-controlled annealing and eventually formed into Co 3 O 4 microcubes@GA composite. GA acts as a three-dimensional conductive network and mechanical skeleton, providing high electrical conductivity and structural stability to the composites. Moreover, the precursor's high porosity and stable structure are retained after annealing treatment. As an anode, the best long cycle life of Co 3 O 4 microcubes@GA was achieved when the graphene oxide (GO) concentration was 3.0 mg ml−1, reaching 1234.9 mAh g−1 after 200 cycles at 1 A g−1 with a coulomb efficiency (CE) of 98.97%. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PRUSSIAN blue
*AEROGELS
*GRAPHENE
*ELECTRIC conductivity
*GRAPHENE oxide
Subjects
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 49
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 162257361
- Full Text :
- https://doi.org/10.1016/j.ceramint.2022.12.023