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Low-temperature synthesized amorphous quasi-high-entropy carbonate electrocatalyst with superior surface self-optimization for efficient water oxidation.
- Source :
-
Ceramics International . Apr2023, Vol. 49 Issue 8, p12156-12165. 10p. - Publication Year :
- 2023
-
Abstract
- Anionic High-entropy materials have seldom been reported as a new library of water oxidation electrocatalysts owing to great difficulty in uniformly distributing multiple elements with different physicochemical properties and harsh synthesis conditions. Herein, a series of amorphous quasi-high-entropy carbonates for the first time is prepared via a facile low-temperature hydrothermal route. The optimized CoCrFeMnMoCO 3 with hydrothermal treatment of 6 h can serve as a promising oxygen evolution reaction (OER) electrocatalyst for water splitting on account of amorphous structure rendering more exposed active sites, superior synergistic effect realizing surface component self-optimization, high-valence ferritic species (Fe(3+δ)+) providing high catalytic activity and high-entropy stabilization guaranteeing long-term OER performance, thus exhibiting the low overpotentials of 302 and 355 mV at the current densities of 10 and 100 mA cm−2, respectively, the small Tafel slope of 36.7 mV dec−1, and excellent durability longer than 38 h, dramatically exceeding its corresponding crystalline counterpart and benchmark RuO 2 catalyst, as well as yielding the current density of 10 mA cm−2 with impressive low voltage of 1.56 V while used as bifunctional electrocatalyst for overall water splitting. This study lights a broad avenue to design other anionic high-entropy materials as promising OER catalysts. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 49
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 162257400
- Full Text :
- https://doi.org/10.1016/j.ceramint.2022.12.067