Ammonia decomposition over Ru catalysts supported on alumina with different crystalline phases.

The effect of the crystalline phase of alumina on ammonia decomposition over alumina-supported ruthenium (Ru) catalysts was examined. Various Ru catalysts supported on different alumina (α-Al 2 O 3 , κ-Al 2 O 3 , θ-Al 2 O 3 , δ-Al 2 O 3 , η-Al 2 O 3 , and γ-Al 2 O 3) were prepared using a wet impregnation method. The prepared catalysts were characterized using inductively coupled plasma-optical emission spectroscopy, N 2 physisorption, X-ray diffraction, transmission electron microscopy, and CO chemisorption. The Ru dispersion for Ru/Al 2 O 3 was reduced without a calcination step in the following order: Ru/α-Al 2 O 3 < Ru/κ-Al 2 O 3 < Ru/θ-Al 2 O 3 < Ru/δ-Al 2 O 3 < Ru/η-Al 2 O 3 < Ru/γ-Al 2 O 3. Among them, Ru/α-Al 2 O 3 showed the highest catalytic activity for ammonia decomposition. Moreover, the effect of calcination temperature before the reduction step was investigated. Ru particle size and morphology were confirmed to change through the calcination process. Ru/κ-Al 2 O 3 with Ru particle sizes ranging between 7 and 8 nm exhibited the highest ammonia decomposition rate among Ru/Al 2 O 3 catalysts calcined at different temperatures and reduced at 573 K. Therefore, Ru dispersion and its morphology, which can be controlled by the support and calcination temperature, are critical factors for hydrogen production through ammonia decomposition over Ru/Al 2 O 3 catalysts. [Display omitted] • NH 3 decomposition was performed over Ru/Al 2 O 3 catalysts. • The effect of the crystalline phases of alumina was evaluated. • The effect of the Ru dispersion and morphology was investigated. • All data support that NH 3 decomposition is a structure sensitive reaction. • The relationship between the catalytic activity and Ru dispersion is discussed. [ABSTRACT FROM AUTHOR]