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Oxygen Vacancies-Rich S-Cheme BiOBr/CdS Heterojunction with Synergetic Effect for Highly Efficient Light Emitting Diode-Driven Pollutants Degradation.
- Source :
-
Nanomaterials (2079-4991) . Mar2023, Vol. 13 Issue 5, p830. 18p. - Publication Year :
- 2023
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Abstract
- Recently, the use of semiconductor-based photocatalytic technology as an effective way to mitigate the environmental crisis attracted considerable interest. Here, the S-scheme BiOBr/CdS heterojunction with abundant oxygen vacancies (Vo-BiOBr/CdS) was prepared by the solvothermal method using ethylene glycol as a solvent. The photocatalytic activity of the heterojunction was investigated by degrading rhodamine B (RhB) and methylene blue (MB) under 5 W light-emitting diode (LED) light. Notably, the degradation rate of RhB and MB reached 97% and 93% in 60 min, respectively, which were better than that of BiOBr, CdS, and BiOBr/CdS. It was due to the construction of the heterojunction and the introduction of Vo, which facilitated the spatial separation of carriers and enhanced the visible-light harvest. The radical trapping experiment suggested that superoxide radicals (·O2−) acted as the main active species. Based on valence balance spectra, Mott-Schottky(M-S) spectra, and DFT theoretical calculations, the photocatalytic mechanism of the S-scheme heterojunction was proposed. This research provides a novel strategy for designing efficient photocatalysts by constructing S-scheme heterojunctions and introducing oxygen vacancies for solving environmental pollution. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 20794991
- Volume :
- 13
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Nanomaterials (2079-4991)
- Publication Type :
- Academic Journal
- Accession number :
- 162385925
- Full Text :
- https://doi.org/10.3390/nano13050830